What can't a firewall protect against

Firewalls can't protect against attacks that don't go through the firewall. Many corporations that connect to the Internet are very concerned about proprietary data leaking out of the company through that route. Unfortunately for those concerned, a magnetic tape can just as effectively be used to export data. Many organizations that are terrified (at a management level) of Internet connections have no coherent policy about how dial-in access via
modems should be protected. It's silly to build a 6-foot thick steel door when you live in a wooden house, but there are a lot of organizations out there buying expensive firewalls and neglecting the numerous other back-doors into their network. For a firewall to work, it must be a part of a consistent overall organizational security architecture. Firewall policies must be realistic, and reflect the level of security in the entire network. For example, a site with top secret or classified data doesn't need a firewall at all: they shouldn't be hooking up to the Internet in the first place, or the systems with the really secret data should be isolated from the rest of the corporate network.
Another thing a firewall can't really protect you against is traitors or idiots inside your network. While an industrial spy might export information through your firewall, he's just as likely to export it through a telephone, FAX machine, or floppy disk. Floppy disks are a far more likely means for information to leak from your organization than a firewall! Firewalls also cannot protect you against stupidity. Users who reveal sensitive information over the
telephone are good targets for social engineering; an attacker may be able to break into your network by completely bypassing your firewall, if he can find a ``helpful'' employee inside who can be fooled into giving access to a modem pool.
Lastly, firewalls can't protect against tunneling over most application protocols to trojaned or poorly written clients. There are no magic bullets, and a firewall is not an excuse to not implement software controls on internal networks or ignore host security on servers. Tunneling ``bad'' things over HTTP, SMTP, and other protocols is quite simple and trivially demonstrated. Security isn't fire and forget.